Burning biodiesel as a fuel is considered to be a “carbon neutral” activity. Explain what is meant by “carbon neutral” in this context.

The source of biodiesel is from plant parts. During the growth and development of these plants, they absorb carbon dioxide from the environment for photosynthesis. During the combustion of biodiesel, the same amount of carbon dioxide is released to the environment.

The net amount of carbon added to the environment from the burning of biodiesel is considered to be zero, hence “carbon neutral”.

Explain, using structure and bonding, why alloys are stronger and harder than pure metals.

Pure metals consist of a lattice of positive ions, arranged in regular pattern, surrounded by a sea of delocalised electrons. When a force is applied, the layers of positive ions slide over one another easily, without disrupting the metallic bonding. This makes the pure metal soft and malleable.

An alloy is a mixture of a pure metal with other elements. The atoms of the added element have a different size from those of the pure metal. This breaks up the regular arrangement of atoms in the pure metal. When a force is applied, the atoms of different sizes cannot slide over one another easily. This makes the alloy stronger and harder.

With reference to the graph, explain the progress of the reaction.

At the start, the gradient of the curve is the steepest. This shows that speed of reaction is the highest at the start. The concentration of the reacting particles is the highest at the start, resulting in highest speed of reaction.

As the reaction progresses, the gradient of the curve decreases. This shows that speed of reaction is slowing down. As the reactants are used up in the reaction, the concentration of reacting particles decreases, resulting in a decrease in speed of reaction.

When the gradient of the curve becomes horizontal, it shows that the reaction has stopped. Either one or all of the reactants have been completely used up, so reaction stopped.

What are the harmful effects of acid rain?

Acid rain speeds up the corrosion of buildings and structures made of limestone or reactive metals, like steel.

Acid rain makes water too acidic, which can be harmful to aquatic organisms.

Acid rain removes essential metal ions needed by plants, such as calcium, potassium, magnesium ions from the soil, affecting the health of plants.

Explain why it is not advisable for farmers to add slaked lime and ammonium-based fertilizers to their crop soil at the same time.

When both substances are added at the same time, they will react to produce a salt, ammonia gas and water.

Slaked lime will be used up in the reaction, hence the acidity of the soil will not be reduced.

Fertilizers will be used up in the reaction. Ammonia gas produced will escape to the surroundings, so nitrogen element, which is needed by the plants for healthy growth, will not be absorbed by the plants.

What are the advantages and disadvantages of the hydrogen fuel cell?

Advantages:

1. The hydrogen fuel cell produces water as the only waste products. No harmful gases are released to surroundings when it is used.

 2. Hydrogen is an abundant resource, if a cost effective method can be used to extract hydrogen from water.

Disadvantages:

1. There is currently no cost effective method of storing the hydrogen gas.

2. There is currently no cost effective method of extracting hydrogen from seawater.

3. The process to obtain hydrogen, either from electrolysis of water, or from cracking of hydrocarbons, produces waste gases and use up large amount of energy.

Explain why two hydrogen atoms and one oxygen atom are involved in a covalent bond to form a H2O molecule.

Each oxygen atom needs to share two electrons to achieve a stable electronic structure of a noble gas.

However, one hydrogen atom can only share one electron to achieve its own stable electronic structure.

Therefore, one oxygen atom will share 2 valence electrons with 2 hydrogen atoms to form the H2O molecule.